Improved efficiency of in-situ combustion by application of submicro metal oxides particles

ZHANG Xian; CHE Hongchang; LIU Yisheng; CHEN Xin

doi:10.13809/j.cnki.cn32-1825/te.2019.04.007

Views : 0 下载量: 23 CSCD: 4 CNKI被引量: 6 Scopus: 0 更多指标

PDF
Export
Share
Collection
Album

Improved efficiency of in-situ combustion by application of submicro metal oxides particles
Issue 4, Pages: 36-40(2019)
Published：2019
DOI： 10.13809/j.cnki.cn32-1825/te.2019.04.007
稿件说明：

移动端阅览

DOI：

ZHANG Xian, CHE Hongchang, LIU Yisheng, et al. Improved efficiency of in-situ combustion by application of submicro metal oxides particles[J]. Petroleum Reservoir Evaluation and Development, 2019, (4): 36-40. DOI： 10.13809/j.cnki.cn32-1825/te.2019.04.007.

摘要

了明确超细过渡金属催化剂对稠油火烧效果的影响

应用热分析及等转化率方法对NiO、α·Fe

和Co

三种超细过渡金属粒子进行火烧氧化动力学评价

并应用优选出的催化剂开展一维火驱实验。实验结果表明

在Co

存在的条件下

稠油活化能降低幅度最大

达41.7%

且Co

催化活性较高

适合作为火驱实验的催化剂。与纯火驱相比

催化条件下原油的高温氧化反应得到强化

氧气利用率提高6.79%

燃烧时间缩短11.8%

燃烧前缘平均温度提高20℃

燃烧前缘最大温度差降低4℃

燃烧更加稳定

且前缘推进速度加快了0.042 cm/min

最终驱油效率提高5.7%

产出油降黏率提高7.2%。研究成果对拓展火烧油层开采稠油的应用具有重要的指导意义。

Abstract

In order to identify the effect of ultra-fine transition metal catalyst on the in-situ combustion of heavy oil

thermal analysis and isoconversional method were used to evaluate the burning oxidation kinetics of three ultra-fine transition metal particles—NiO

α·Fe

and Co

. And then

one-dimensional in-situ combustion experiment was carried out by the optimized catalyst. The experimental results showed that

in the presence of Co

the activation energy of heavy oil decreased the m

ost

up to 41.7 %. Meanwhile

had higher catalytic activity

that made it suitable for in-situ combustion experiment. Compared to conventional in-situ combustion

high temperature oxidation reaction of crude oil was enhanced under the catalytic condition of Co

. The oxygen utilization ratio increased by 6.79 %

the combustion time shortened by 11.8 %

the average temperature of the leading edge of combustion increased by 20 ℃

the maximum temperature difference of the leading edge of combustion reduced by 4 ℃

the combustion was more stable

the advance speed of the leading edge increased by 0.042 cm/min

the final oil displacement efficiency increased by 5.7 %

and the viscosity reduction rate of the produced oil increased by 7.2 %. The research results have important guiding significance for expanding the application of heavy oil recovery by in-situ combustion.

关键词

Keywords

references

Patrick G. O. Ossai,Princewill N. Ohia,Boniface Obah,Ugochukwu I. Duru.In situ combustion methods: Applicability to heavy oil reservoirs in the Niger Delta[J].Petroleum Science and Technology,2017.

Y. Hamedi Shokrlu,Y. Maham,X. Tan,T. Babadagli,M. Gray.Enhancement of the efficiency of in situ combustion technique for heavy-oil recovery by application of nickel ions[J].Fuel,2013.

Catalytic Effects of Metallic Additives on The Combustion Properties of Crude Oils by Thermal Analysis Techniques[J].Journal of Thermal Analysis and Calorimetry,2001(3).

关文龙,张霞林,席长丰,王晓春,杨凤祥,施小荣,李秋.稠油老区直井火驱驱替特征与井网模式选择[J].石油学报,2017(08).

鹿剑,盛剑平,骆建敏,宿新泰.油溶性纳米Fe_3O_4催化稠油水热裂解降黏[J].广东化工,2017(06).

石岩松,赵法军.应用于稠油降粘改质中的超分散纳米催化剂的研究进展与前景展望[J].当代化工,2015(12).

刘海,潘一,冷俊.国内外火烧油层研究进展与应用[J].当代化工,2015(03).

李巍,刘永建,田歆源,耿志刚.重油中添加金属催化剂的火烧油层实验[J].油田化学,2015(01).

樊铖,张强,魏飞.稠油的可控氧化热采:MnO_2催化剂上的重油低温氧化分解行为(英文)[J].催化学报,2015(02).

唐君实,关文龙,梁金中,江航,王伯军.热重分析仪求取稠油高温氧化动力学参数[J].石油学报,2013(04).

王元基,何江川,廖广志,王正茂.国内火驱技术发展历程与应用前景[J].石油学报,2012(05).

程海清,赵庆辉,刘宝良,吴拓,彭旭.超稠油燃烧基础参数特征研究[J].特种油气藏,2012(04).

张方礼.火烧油层技术综述[J].特种油气藏,2011(06).

杨俊印.火烧油层(干式燃烧)室内实验研究[J].特种油气藏,2011(06).

柴利文,金兆勋.中深厚层稠油油藏火烧油层试验研究[J].特种油气藏,2010(03).

关文龙,马德胜,梁金中,李春涛,席长丰,张霞林.火驱储层区带特征实验研究[J].石油学报,2010(01).

蔡文斌,谢志勤,王霞.湿式燃烧的实验研究[J].特种油气藏,2001(02).

胡士清,白国斌,赵春梅.火烧油层技术在庙5块低渗透稠油油藏中的应用[J].特种油气藏,1998(04).