In order to study the simulation effects of different isothermal adsorption models on isothermal adsorption experiments and better describe the adsorption rule of shale methane
isothermal adsorption experiments were carried out on seven core samples from well PY1 in southeast of Sichuan Basin. The experimental results showed that the maximum excess adsorption amount was positively correlated with the organic matter content
and the maximum correlation coefficient was 0.859 4
while it was negatively correlated with clay minerals. The experimental results were simulated by different models. The simulation results of different models were quite different. Among them
the correlation coefficient fitted by the Langmuir model was the best
while the maximum excess adsorption amount obtained by the SDR model was the largest. Followed by that was the fixed Langmuir model. Both the SDR model and the modified Langmuir model had corrected the excess adsorption amount of the experimental results
but from the correction results
the adsorption phase density obtained by the SDR model was the most reasonable. Finally
the fixed density correction Langmuir model and the SDR model were considered to describe the adsorption of methane in the shale more accurately
which could guide the calculation of the shale adsorption gas content better.
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Hui Tian,Tengfei Li,Tongwei Zhang,Xianming Xiao.Characterization of methane adsorption on overmature Lower Silurian–Upper Ordovician shales in Sichuan Basin, southwest China: Experimental results and geological implications[J].International Journal of Coal Geology,2016.
Tongwei Zhang,Geoffrey S. Ellis,Stephen C. Ruppel,Kitty Milliken,Rongsheng Yang.Effect of organic-matter type and thermal maturity on methane adsorption in shale-gas systems[J].Organic Geochemistry,2012.
Ronny Pini,Stefan Ottiger,Luigi Burlini,Giuseppe Storti,Marco Mazzotti.Sorption of carbon dioxide, methane and nitrogen in dry coals at high pressure and moderate temperature[J].International Journal of Greenhouse Gas Control,2009(1).
Katsuyuki Murata,Jin Miyawaki,Katsumi Kaneko.A simple determination method of the absolute adsorbed amount for high pressure gas adsorption[J].Carbon,2002(3).