SHI Liyan, LI Weibo, KANG Qinqin, et al. Experimental study on variation of apparent resistivity in CH4-coal adsorption/desorption process[J]. Petroleum Reservoir Evaluation and Development, 2022, (4): 572-579. DOI: 10.13809/j.cnki.cn32-1825/te.2022.04.004.
In order to reveal the change law of apparent resistivity in the process of CH
4
-coal adsorption/desorption of different macroscopic coal petrology compositions
the No.4 coal seam of the Jurassic Yan'an Formation in Dafosi coal mine is taken as the experimental object. By the proximate analysis and apparent resistivity measurement experiments of differe
nt coal samples (the durain
vitrain and mixed samples) with different water content (air dry basis sample
natural water absorption sample and samples dried at 378.15 K) of coal
the relationship between the apparent resistivity
methane adsorption and pressures is studied. The experimental results found that when compared to the vitrain
the durain has higher fixed carbon content
but lower ash content and moisture. The initial resistivity of the samples dried at 378.15 K of the durain is the largest. The influence of the adsorption of methane on the resistivity of the coal body is manifested in that with the adsorption of methane
the apparent resistivity of coal is significantly reduced. During the pressure increasing process that is the process of adsorption
the coal resistivity has a quadratic function relationship with the pressure and the amount of adsorption. The reason is that methane adsorption heat release
coal body expansion
and the spread of water on the inner wall of the pore throat causes the apparent resistivity to decrease. Due to methane adsorption
gas-water replacement occurs on the surface of the coal matrix
free water dissolves soluble minerals
and the ion concentration increases. In the process of adsorption
the apparent resistivity of coal decreases
but due to the limited soluble minerals and the hydrophobicity of coal
the resistivity of coal tends to be stable in the later stage of adsorption. During the depressurization process
that is the process of desorption
since the shrinkage of the coal matrix after expansion is irreversible (deformation)
the apparent resistivity of the coal body cannot be restored to its initial value. Compared to the durain
the pore connectivity of vitrain is poor
but the pore throat curvature is larger
when the number of charged particles in the double electric layer is high and aggregated in piles. This eventually leads to better electrical conductivity of vitrain than durain under the same conditions