YANG Yu, XU Qilin, LIU Ronghe, et al. Phase equilibrium law of CO2 storage in depleted gas reservoirs[J]. Petroleum Reservoir Evaluation and Development, 2023, (3): 280-287. DOI: 10.13809/j.cnki.cn32-1825/te.2023.03.002.
Phase equilibrium law of CO2 storage in depleted gas reservoirs
injection and storage of a single well in depleted gas reservoirs
the injected CO
2
causes the rebalance among gas
water and solid
and the accompanying CO
2
dissolution
water evaporation and salting out affect the physical properties of the formation near this well. Therefore
taking depleted gas reservoir
in western Sichuan as an example
the SRK-HV equation and salting out model are used to analyze the three-phase change rule during the CO
2
injection process of the depleted gas reservoir. The researches show that during the CO
2
injection process in the constant volume system
with the increase of the number of mole of CO
2
the gas phase pressure increases
the CO
2
solubility gradually increases
and the mole fraction of H
2
O in the gas phase gradually decreases
but the total number of mole of H
2
O in the gas phase continuously increases
indicating that the total evaporation of water increases. In addition
the water phase volume reduction caused by water evaporation is smaller than the initial water phase volume
so the increase of formation water salinity is small. The dissolution of CO
2
accelerates the precipitation of CaCO
3
while inhibiting the precipitation of CaSO
4
and CaSO
4
·2H
2
O. In calcium chloride type formation water
CaCO
3
and CaSO
4
will be separated with the increase of salinity. The research results has certain reference significance for the study of water evaporation and salting out during CO